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Direct Evidence of Phosphate Binding on Ferritin Based on Quantitative Elemental Analysis at the Single-Particle Level

https://doi.org/10.1093/mam/ozae044.830

Zhang, Xiaoben; Zhuang, Wen; Zaluzec, Nestor J; Chen, Junhong (July 2024, Microscopy and Microanalysis)

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Bismuth-Modulated Surface Structural Evolution of Pd ₃ Bi Intermetallic Alloy Catalysts for Selective Propane Dehydrogenation and Acetylene Semihydrogenation

https://doi.org/10.1021/acscatal.2c00642

Zhang, Wenqing; Zhang, Xiaoben; Wang, Jianyang; Ghosh, Arnab; Zhu, Jie; LiBretto, Nicole J.; Zhang, Guanghui; Datye, Abhaya K.; Liu, Wei; Miller, Jeffrey T. (September 2022, ACS Catalysis)

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Structural and Catalytic Properties of Isolated Pt ²⁺ Sites in Platinum Phosphide (PtP ₂ )

https://doi.org/10.1021/acscatal.1c03970

Kou, Jiajing; Zhu Chen, Johnny; Gao, Junxian; Zhang, Xiaoben; Zhu, Jie; Ghosh, Arnab; Liu, Wei; Kropf, A. Jeremy; Zemlyanov, Dmitry; Ma, Rui; et al (November 2021, ACS Catalysis)

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Reversible loss of core–shell structure for Ni–Au bimetallic nanoparticles during CO2 hydrogenation

https://doi.org/10.1038/s41929-020-0440-2

Zhang, Xiaoben; Han, Shaobo; Zhu, Beien; Zhang, Guanghui; Li, Xiaoyan; Gao, Yi; Wu, Zhaoxuan; Yang, Bing; Liu, Yuefeng; Baaziz, Walid; et al (April 2020, Nature Catalysis)

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Diffusion-Limited Formation of Nonequilibrium Intermetallic Nanophase for Selective Dehydrogenation

https://doi.org/10.1021/acs.nanolett.9b00994

Zhang, Guanghui; Ye, Chenliang; Liu, Wei; Zhang, Xiaoben; Su, Dangsheng; Yang, Xin; Chen, Johnny Zhu; Wu, Zhenwei; Miller, Jeffrey T. (July 2019, Nano Letters)

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Identification of the structure of the Bi promoted Pt non-oxidative coupling of methane catalyst: a nanoscale Pt ₃ Bi intermetallic alloy

https://doi.org/10.1039/C8CY02171F

Zhu Chen, Johnny; Wu, Zhenwei; Zhang, Xiaoben; Choi, Slgi; Xiao, Yang; Varma, Arvind; Liu, Wei; Zhang, Guanghui; Miller, Jeffrey T. (March 2019, Catalysis Science & Technology)

Recently, stable non-oxidative conversion of methane (NOCM) for up to 8 h with a C 2 selectivity greater than 90% has been reported over Pt–Bi/ZSM-5 at moderate temperatures (600–700 °C). In this study, we show that the structure of the bimetallic nanoparticles on Pt–Bi/ZSM-5 catalyst is similar to Pt–Bi/SiO 2 . EXAFS indicates the formation of Pt-rich bimetallic Pt–Bi nanoparticles with Pt–Bi bond distance of 2.80 Å. The XRD spectra (on SiO 2 ) are consistent with cubic, intermetallic surface Pt 3 Bi phase on a Pt core. The Pt 3 Bi structure is not known in the thermodynamic phase diagram. In all catalysts, only a small fraction of Bi alloys with Pt. At high Bi loadings, excess Bi reduces at high temperature, covering the catalytic surface leading to a loss in activity. At lower Bi loadings with little excess Bi, the Pt 3 Bi surface is effective for non-oxidative coupling of CH 4 (on ZSM-5) and propane dehydrogenation (on SiO 2 ).
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